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Department of Chemistry

Bloch Research Group

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Publications

  1. Solvent and Ligand Control Over the Assembly of Coordination Cage-Based Metal-Organic Frameworks. Taggart, G. A.; Montone, C. M.; Dworzak, M. R.; Yap, G. P. A; Bloch, E. Submitted.
  2. Monitoring the Stability of Porous Coordination Cages During the Photoreduction of Porous Salts. Hoq, J.; Korathotage, K.; Dworzak, M. R.; Yap, G. P. A.; Bloch, E. D. Submitted.
  3. Electrochemically-Mediated Synthesis of Porous Copper(II) Coordination Cages via Anodic Dissolution. Antonio, A. M.; Bloch, E. D. Submitted.
  4. The Role of Solvent Decomposition in the Synthesis and Composition of Porous Zirconium-Based Coordination Cages. Skalla, R. X.; Montone, C. M.; Pink, M.; Bloch, E. D. Submitted.
  5. Growth and Metallation of Optically Transparent Thin Films of Porphyrin-Based Porous Salts. Simmons, J. D.; Sarkar, S.; Ezazi, A. A.; Sur, A.; Iverson, E. T.; Morey, M. N.; Chivington, A. D.; Grunion, J. C.; Powers, D. C.; Bloch, E. D. Submitted.
  6. Manipulation of Charged Porous Cages as Tunable Platforms for Selective Gas Adsorption. Deegan, M. M.; Antonio, A. M.; Korman, K. J.; Ezazi, A. A.; Yap, G. P. A.; Powers, D. C.; Bloch, E. D. Submitted.
  7. Post-Synthetic Modification of Amine-Functionalized Permanently Porous Coordination Cages. Hoq, J.; Dworzak, M. R.; Dissanayake, D.; Skalla, R. X.; Yamamoto, N.; Bloch, E. D. Chem. Commun. 2025, 61, 1641-1644.
  8. Tunable Synthesis of Heteroleptic Zirconium-Based Porous Coordination Cages. Morey, M. N.; Montone, C. M.; Dworzak, M. R.; Yap, G. P. A.; Bloch, E. D. Chem. Sci. 2025, 16, 816-823.
  9. Selective Gas Adsorption in Permanently Microporous Coordination Cages with Exposed Metal Sites. Korathotage, K.; Yamamoto, N.; Bloch, E. D. Inorg. Chem. 2024, 63, 23698-23704.
  10. Solvent-Free Mechanochemistry for the Preparation of Mixed-Ligand Cuboctahedral Porous Coordination Cages. Hoq, J.; Bloch, E. D. Chem. Commun. 2024, 60, 6945-6948.
  11. Increasing the Stability of Calixarene-Capped Porous Cages Through Coordination Sphere Tuning. Dey, A.; Dworzak, M. R.; Korathotage, K. D. P.; Ghosh, M.; Hoq, J.; Montone, C. M.; Yap, G. P. A; Bloch, E. D. Dalton Trans. 2024, 53, 4005-4009.
  12. Post-Synthetic Modification of Calixarene-Based Porous Coordination Cages. Dworzak, M. R.; Sampson, J.; Montone, C. M.; Korman, K. J.; Yap, G. P. A.; Bloch, E. D. Chem. Mater. 2024, 36, 752-758.
  13. Aerosol Deposition of Porous Metal-Organic Materials onto Diverse Solid Supports. Montone, C. M.; Bloch, E. D. Mater. Adv. 2024, 5, 131-135.
  14. Synthesis of Long Chain Oxygenates via Aldol Condensation of Furfural and Acetone over Metal-Organic Frameworks. Goculdas, T. B.; Korathotage, K. D. P.; Montone, C. M; Sadula, S.; Bloch, E. D.; Vlachos, D. ACS Appl. Mater. Interfaces 2023, 15, 57070-57078.
  15. Unlocking Solid-State Organometallic Photochemistry with Optically Transparent, Porous Salt Thin Films. Sur, A.; Simmons, J. D.; Ezazi, A. A.; Korman, K. J.; Sarkar, S.; Bloch, E. D.; Powers, D. C. J. Am. Chem. Soc. 2023, 145, 25068-25073.
  16. Covalent Modification of Surfaces with Porous Coordination Cages. Montone, C. M.; Dworzak, M. R.; Yap, G. P. A.; Bloch, E. D. J. Mater. Chem. A 2023, 11, 23888-23894.
  17. Forum on Metal-Organic Frameworks for Energy Storage Applications. Bloch, E. D.; Hosono, N.; Rossin, A. ACS Appl. Energy Mater. 2023, 6, 9026.
  18. Adaptive Pore Opening to Form Tailored Adsorption Sites in a Cooperatively Flexible Framework Enables Record Inverse Propane/Propylene Separation. Klein, R. A.; Bingel, L. W.; Halder, A.; Carter, M.; Trump, B. A.; Bloch, E. D.; Zhou, W.; Walton, K. S.; Brown, C. M.; McGuirk, C. M. J. Am. Chem. Soc. 2023, 145, 21955-21965.
  19. Optimizing Volumetric Surface Area of UiO-66 and Its Functionalized Analogs Through Compression. Kuznicki, A.; Bloch, E. D. RSC Advances 2023, 13, 26892-26895.
  20. Rapid Post-Synthetic Modification of Porous Coordination Cages with Copper-Catalyzed Click Chemistry. Dworzak, M. R.; Montone, C. M.; Halaszynski, N. I.; Yap, G. P. A.; Kloxin, C. J.; Bloch, E. D. Chem. Commun. 2023, 59, 8977-8990.
  21. Aluminum-Based Metal-Organic Framework Nanoparticles as Pulmonary Vaccine Adjuvants. Stillman, Z. S.; Decker, G. E.; Dworzak, M. R.; Bloch, E. D.; Fromen, C. A. J. Nanobiotechnology 2023, 21, 39.
  22. Porous Salts as Platforms for Heterogeneous Catalysis. Korman, K. J.; Dworzak, M. R.; Yap, G. P. A.; Bloch, E. D. Small 2023, 19, 2207507.
  23. Monitoring the Solution Persistence of Porous Coordination Cages with Diffusion NMR Spectroscopy and Cryogenic Transmission Electron Microscopy. Taggart, G. A.; Guliyeva, A.; Kim, K.; Yap, G. P. A.; Pochan, D. J.; Epps, T. H.; Bloch, E. D. J. Phys. Chem. C 2023, 127, 2379-2386.
  24. Hydrogen Storage in Porous Cages. Deegan, M. M.; Lorzing, G. R.; Korman, K. J.; Rowland, C. A.; Dworzak, M. R.; Antonio, A. M.; Bloch, E. D. ACS Mater. Au 2023, 3, 66-74.
  25. Anion Binding as a Strategy for the Synthesis of Porous Salts. Antonio, A. M.; Dworzak, M. R.; Korman, K. J.; Yap, G. P. A.; Bloch, E. D. Chem. Mater. 2022, 34, 10823-10831.
  26. Controlling Phase in Low-Nuclearity Calixarene-Capped Coordination Cages with Ligand Functionalization. Dworzak, M. R.; Rowland, C. A.; Yap, G. P. A.; Bloch, E. D. CrystEngComm, 2022, 24, 6315-6319.
  27. Utilization of a Mixed-Ligand Strategy to Tune the Properties of Cuboctahedral Porous Coordination Cages. Antonio, A. M.; Korman, K. J.; Deegan, M. M.; Taggart, G. A.; Yap, G. P. A.; Bloch, E. D. Inorg. Chem. 2022, 61, 4609-4617.
  28. Templated Synthesis of Zirconium(IV)-Based Metal-Organic Layers (MOLs) with Accessible Chelating Sites. Gimeno-Fonquernie, P.; Liang, W.; Albalad, J.; Kuznicki, A.; Price, J. R.; Bloch, E. D.; Doonan, C. J.; Sumby, C. J. Chem. Commun. 2022, 58, 957-960.
  29. Elaboration of Porous Salts. Gosselin, A. J.; Antonio, A. M.; Korman, K. J.; Deegan, M. M.; Yap, G. P. A.; Bloch, E. D. J. Am. Chem. Soc. 2021, 143, 14956-14961.
  30. Facile and Rapid Room-Temperature Electrosynthesis and Controlled Surface Growth of Fe-MIL-101 and Fe-MIL-101-NH2. Wu, W.; Decker, G. E.; Weaver, A. E.; Arnoff, A. I.; Bloch, E. D.; Rosenthal, J. ACS Cent. Sci. 2021, 7, 1427-1433.
  31. Tuning Water Adsorption, Stability, and Phase in Fe-MIL-101 and Fe-MIL-88 Analogs with Amide Functionalization. Kuznicki, A.; Lorzing, G. R.; Bloch, E. D. Chem. Commun. 2021, 57, 8312-8315.
  32. Using Helium Pycnometry to Study the Apparent Densities of Metal-Organic Frameworks. Decker, G. E.; Bloch, E. D. ACS Appl. Mater. Interfaces 2021, 13, 51925-51932.
  33. Stabilizing Porosity in Organic Cages Through Coordination Chemistry. Deegan, M. M.; Bhattacharjee, R.; Caratzoulas, S.; Bloch, E. D. Inorg. Chem. 2021, 60, 7044-7050.
  34. Synthesis and Characterization of an Isoreticular Family of Calixarene-Capped Porous Coordination Cages. Dworzak, M. R.; Deegan, M. M.; Yap, G. P. A.; Bloch, E. D. Inorg. Chem. 2021, 60, 5607-5616.
  35. Synthesis, Characterization, and Polymerization of Capped Paddlewheel Porous Cages. Deegan, M. M.; Bloch, E. D. Dalton Trans. 2021, 50, 3127-3131.
  36. Gas Storage in Porous Molecular Materials. Deegan, M. M.; Dworzak, M. R.; Gosselin, A. J.; Korman, K. J.; Bloch, E. D. Chem. Eur. J. 2021, 27, 4531-4547. Invited Contribution.
  37. Manipulating Solvent and Solubility in the Synthesis, Activation, and Modification of Permanently Porous Coordination Cages. Deegan, M. M.; Antonio, A. M.; Taggart, G. A.; Bloch, E. D. Coord. Chem. Rev. 2021, 430, 213679. Invited Contribution.
  38. Porous Metal-Organic Alloys Based on Soluble Coordination Cages. Antonio, A. M.; Korman, K. J.; Yap, G. P. A.; Bloch, E. D. Chem. Sci. 2020, 11, 12540-12546.
  39. Elucidating the Structure of the Metal-Organic Framework Ru-HKUST-1. Lorzing, G. R.; Balto, K. P.; Antonio, A. M.; Trump, B. A.; Brown, C. M.; Bloch, E. D. Chem. Mater. 2020, 32, 7710-7715.
  40. Using Low-Pressure Methane Adsorption Isotherms for Higher-Throughput Screening of Methane Storage Materials. Korman, K. J.; Decker, G. E.; Deegan, M. M.; Dworzak, M. R.; Antonio, A. M.; Taggart, G. A.; Bloch, E. D. ACS Appl. Mater. Interfaces 2020, 12, 40318-40327.
  41. Evaluating UiO-66 Metal-Organic Framework (MOF) Nanoparticles as Acid-Sensitive Carriers for Pulmonary Drug Delivery Applications. Jarai, B. M.; Stillman, Z.; Attia, L.; Decker, G. E.; Bloch, E. D.; Fromen, C. A. ACS Appl. Mater. Interfaces 2020, 12, 38989-39004.
  42. Design and Synthesis of Aryl-Functionalized Carbazole-Based Porous Coordination Cages. Rowland, C. A.; Lorzing, G. R.; Bhattacharjee, R.; Caratzoulas, S.; Yap, G. P. A.; Bloch, E. D. Chem. Commun. 2020, 56, 9352-9355.
  43. Synthesis and Characterization of Low-Nuclearity Lantern-Type Porous Coordination Cages. Taggart, G. A.; Lorzing, G. R.; Dworzak, M. R.; Yap, G. P. A.; Bloch, E. D. Chem. Commun. 2020, 56, 8924-8927. Invited Contribution-Emerging Investigators 2020.
  44. Ligand-Based Phase Control in Porous Zirconium Coordination Cages. Gosselin, A. J.; Decker, G. E.; McNichols, B. W.; Baumann, J. E.; Yap, G. P. A.; Sellinger, A.; Bloch, E. D. Chem. Mater. 2020, 32, 5872-5878.
  45. Permanently Microporous Metal-Organic Polyhedra. Gosselin, A. J.; Rowland, C. A.; Bloch, E. D. Chem. Rev. 2020, 120, 8987-9014. Invited Contribution-Thematic Issue 2020 – Porous Framework Chemistry.
  46. Novel Syntheses of Carbazole-3,6-Dicarboxylate Ligands and Their Utilization for Porous Coordination Cages. Rowland, C. A.; Yap, G. P. A.; Bloch, E. D. Dalton Trans. 2020, 49, 16340-16347. Invited Contribution-Special Issue: New Talent: Americas.
  47. Tuning the Porosity, Solubility, and Gas Storage Properties of Cuboctahedral Coordination Cages via Amide or Ester Functionalization. Taggart, G. A.; Antonio, A. M.; Lorzing, G. R.; Yap, G. P. A.; Bloch, E. D. ACS Appl. Mater. Interfaces 2020, 12, 24913-24919.
  48. A Charged Coordination Cage Based Porous Salt. Gosselin, A. J.; Decker, G. E.; Antonio, A. M.; Lorzing, G. R.; Yap, G. P. A.; Bloch, E. D. J. Am. Chem. Soc. 2020, 142, 9594-9598.
  49. Structure and Redox Tuning of Gas Adsorption Properties in Calixarene-Supported Fe(II)-Based Porous Cages. Deegan, M. M.; Ahmed, T. S.; Yap, G. P. A.; Bloch, E. D. Chem. Sci. 2020, 11, 5273-5279.
  50. Atomically Precise Crystalline Materials Based on Kinetically Inert Metal Ions by Reticular Mechanopolymerization. Gao, W.-Y.; Sur, A.; Wang, C.-H.; Lorzing, G. R.; Antonio, A. M.; Taggart, G. A.; Ezazi, A. A.; Bhuvanesh, N.; Bloch, E. D.; Powers, D. C. Angew. Chem. Int. Ed. 2020, 59, 10878-10883.
  51. MOF-Mimetic Molecules: Carboxylate-Based Supramolecular Complexes as Molecular Metal-Organic Framework Analogues. Decker, G. E.; Lorzing, G. R.; Deegan, M. M.; Bloch, E. D. J. Mater. Chem. A 2020, 8, 4217-4229. Invited Contribution.
  52. Neutron Diffraction Structural Study of CO2 Binding in Mixed-Metal CPM-200 Metal-Organic Frameworks. Campanella, A. J.; Trump, B. A.; Gosselin, A. J.; Bloch, E. D.; Brown, C. M. Chem. Commun. 2020, 56, 2574-2577.
  53. Design and Synthesis of Capped-Paddlewheel-Based Porous Coordination Cages. Lorzing, G. R.; Gosselin, A. J.; Lindner, B. S.; Bhattacharjee, R.; Yap, G. P. A.; Caratzoulas, S.; Bloch, E. D. Chem. Commun. 2019, 55, 9527-9530.
  54. Understanding Gas Storage in Cuboctahedral Porous Coordination Cages. Lorzing, G. R.; Gosselin, A. J.; Trump, B. A.; York, A. H. P.; Sturluson, A.; Rowland, C. A.; Yap, G. P. A.; Brown, C. M.; Simon, C. M.; Bloch, E. D. J. Am. Chem. Soc. 2019, 141, 12128-12138.
  55. Electrochemically-Mediated Syntheses of Titanium(III)-Based Metal-Organic Frameworks. Antonio, A. M.; Rosenthal, J.; Bloch, E. D. J. Am. Chem. Soc. 2019, 141, 11383-11387.
  56. Controlling Size, Defectiveness, and Fluorescence in Nanoparticle UiO-66 Through Water and Ligand Modulation. Decker, G. E.; Stillman, Z.; Attia, L.; Fromen, C. A.; Bloch, E. D. Chem. Mater. 2019, 31, 4831-4839.
  57. High-Pressure Methane Storage and Selective Gas Adsorption in a Cyclohexane-Functionalized Porous Organic Cage. Charles, C. D.; Bloch, E. D. Supramolecular Chemistry 2019, 31, 508-513. Invited Contribution-Special Issue: Emerging Supramolecular Chemists in the United States.
  58. Mechanochemical Synthesis of Two-Dimensional Metal-Organic Frameworks. Barreda, O.; Lorzing, G. R.; Bloch, E. D. Powder Diffraction 2019, 34, 119-123. Invited Contribution-Special Issue: Metal-Organic Frameworks.
  59. Methane Storage in Paddlewheel-Based Porous Coordination Cages. Rowland, C. A.; Lorzing, G. R.; Gosselin, A. J.; Trump, B. A.; Yap, G. P. A.; Brown, C. M.; Bloch, E. D. J. Am. Chem. Soc. 2018, 140, 11153-11157.
  60. Gas Adsorption in an Isostructural Series of Pillared Coordination Cages. Gosselin, A. J.; Lorzing, G. R.; Trump, B. A.; Brown, C. M.; Bloch, E. D. Chem. Commun. 2018, 54, 6392-6395.
  61. Mechanochemical Synthesis of Porous Molecular Assemblies. Barreda, O.; Taggart, G. A.; Rowland, C. A.; Yap, G. P. A.; Bloch, E. D. Chem. Mater. 2018, 30, 3975-3978.
  62. Design and Synthesis of Porous Nickel(II) and Cobalt(II) Cages. Gosselin, A. J.; Rowland, C. A.; Balto, K. P.; Yap, G. P. A.; Bloch, E. D. Inorg. Chem. 2018, 57, 11847-11850.
  63. Ligand-Based Phase Control in Porous Molecular Assemblies. Barreda, O.; Bannwart, G.; Yap, G. P. A.; Bloch, E. D. ACS Appl. Mater. Interfaces 2018, 10, 11420-11424.
  64. Selective Gas Adsorption in Highly Porous Chromium(II)-Based Metal-Organic Polyhedra. Lorzing, G. R.; Trump, B. A.; Brown, C. M.; Bloch, E. D. Chem. Mater. 2017, 29, 8583-8587.
  65. Permanent Porosity in the Room-Temperature Magnet and Magnonic Material V(TCNE)2. Park, J. G.; Jaramillo, D. E.; She, Y.; Jiang, H. Z. H.; Yusuf, H.; Furukawa, H.; Bloch, E. D.; Comrade, D. S.; Miller, J. S.; Harris, T. D.; Johnston-Halperin, E.; Flatte, M. E.; Long, J. R. ACS Cent. Sci. 2023, 9, 777-786.
  66. Solvent-Induced Spin-State Change in Copper Corroles. Lemon, C. M.; Maher, A. G.; Anderson, B. L.; Bloch, E. D.; Huynh, M.; McCollar, A. L.; Nocera, D. G. Inorg. Chem. 2022, 61, 20288-20298.
  67. Oxygen Activation at a Dicobalt Centre of a Dipyridylethane Naphthyridine Complex. Brodsky, C. N.; Passard, G.; Ullman, A. M.; Jaramillo, D. E.; Bloch, E. D.; Huynh, M.; Costentin, C.; Nocera, D. G. Dalton Trans. 2018, 47, 11903-11908.
  68. An Experimental and Computational Study of CO2 Adsorption in the Sodalite-Type M-BTT (M = Cr, Mn, Fe, Cu) Metal-Organic Frameworks Featuring Open Metal Sites. Asgari, M.; Jawahery, S.; Bloch, E. D.; Hudson, M. R.; Flacau, R.; Vlaisavljevich, B.; Boyd, P. G.; Smit, B.; Long, J. R.; Brown, C. M.; Queen, W. L. Chem. Sci. 2018, 9, 4579-4588.
  69. Structurally Characterized Terminal Manganese(IV) Oxo Tris(alkoxide) Complex. Halbach, R. L.; Gygi, D.; Bloch, E. D.; Anderson, B. L.; Nocera, D. G. Chem. Sci. 2018, 9, 4524-4528.
  70. Separation of Xylene Isomers through Multiple Metal Site Interactions in Metal-Organic Frameworks. Gonzalez, M. I.; Kapelewski, M. T.; Bloch, E. D.; Milner, P. J.; Reed, D. A.; Hudson, M. R.; Mason, J. A.; Barin, G.; Brown, C. M.; Long, J. R. J. Am. Chem. Soc. 2018, 140, 3412-3422.
  71. Structural Characterization of Framework-Gas Interactions in the Metal-Organic Framework Co2(dobdc) by in situ Single-Crystal X-ray Diffraction. Gonzalez, M. I.; Mason, J. A.; Bloch, E. D.; Teat, S. J.; Gagnon, K. J.; Morrison, G. Y.; Queen, W. L.; Long, J. R. Chem. Sci. 2017, 8, 4387-4398.
  72. Metal Insertion in a Methylamine-Functionalized Zirconium Metal-Organic Framework for Enhanced Carbon Dioxide Capture. Gomora-Figueroa, A. P.; Mason, J. A.; Gonzalez, M. I.; Bloch, E. D.; Meihaus, K. R. Inorg. Chem. 2017, 56, 4308-4316.
  73. Hydrogen Storage and Selective, Reversible O2 Adsorption in a Metal-Organic Framework with Open Chromium(II) Sites. Bloch, E. D.; Queen, W. L.; Hudson, M. R.; Mason, J. A.; Xiao, D. J.; Murray, L. J.; Flacau, R.; Brown, C. M.; Long, J. R. Angew. Chem. Int. Ed. 2016, 55, 8605-8609.
  74. Hydrogen Storage in the Expanded Pore Metal-Organic Frameworks M2(dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn). Gygi, D.; Bloch, E. D.; Mason, J. A.; Hudson, M. R.; Gonzalez, M. I.; Siegelman, R. L.; Queen, W. L.; Brown, C. M.; Long, J. R. Chem. Mater. 2016, 28, 1128-1138.
  75. Electronic Structure of Copper Corroles. Lemon, C. M.; Huynh, M.; Maher, A. G.; Anderson, B. L.; Bloch, E. D.; Powers, D. C.; Nocera, D. G. Angew. Chem. Int. Ed. 2016, 55, 2176-2180.
  76. Influence of Solvent-like Side Chains on the Adsorption of Light Hydrocarbons in Metal-Organic Frameworks. Schneemann, A.; Bloch, E. D.; Henke, S.; Llewellyn, P. L.; Long, J. R.; Fischer, R. A. Chem. Eur. J. 2015, 21, 18764-18769.
  77. Critical Factors Driving the High Volumetric Uptake of Methane in Cu3(btc)2. Hulvey, Z.; Vlaisavljevich, B.; Mason, J. A.; Tsivion, E.; Dougherty, T. P.; Bloch, E. D.; Head-Gordon, M.; Smit, B.; Long, J. R.; Brown, C. B. J. Am. Chem. Soc. 2015, 137, 10816-10825.
  78. Carbohydrate-Mediated Purification of Petrochemicals. Holcroft, J. M.; Hartlieb, K. J.; Moghadam, P. Z.; Bell, J. G.; Barin, G.; Ferris, D. P.; Bloch, E. D.; Algaradah, M. M.; Nassar, M. S.; Botros, Y. Y.; Thomas, K. M.; Long, J. R.; Snurr, R. Q.; Stoddart, J. F. J. Am. Chem. Soc. 2015, 137, 5706-5719.
  79. Gradual Release of Strongly-Bound Nitric Oxide from Fe2(NO)2(dobdc). Bloch, E. D.; Queen, W. L.; Chavan, S.; Wheatley, P. S.; Zadrozny, J. M.; Morris, R.; Brown, C. M.; Lamberti, C.; Bordiga, S.; Long, J. R. J. Am. Chem. Soc. 2015, 137, 3466-3469.
  80. Single-Crystal-to-Single-Crystal Metallation of a Metal-Organic Framework: A Route Towards Structurally Well-Defined Heterogeneous Catalysts. Gonzalez, M. I.; Bloch, E. D.; Teat, S. J.; Long, J. R. Inorg. Chem. 2015, 54, 2995-3005.
  81. Cooperative Insertion of CO2 in Diamine-Appended Metal-Organic Frameworks. McDonald, T. M.; Mason, J. A.; Kong, X.; Bloch, E. D.; Gygi, D.; Dani, A.; Crocellà, V.; Giordanino, F.; Odoh, S. O.; Dridell, W.; Vlaisavljevich, B.; Dzubak, A. L.; Poloni, R.; Schnell, S. K.; Planas, N.; Lee, K.; Pascal, T.; Wan, L. F.; Prendergast, D.; Neaton, J. B.; Smit, B.; Kortright, J. B.; Gagliardi, L.; Bordiga, S.; Reimer, J. A.; Long, J. R. Nature 2015, 519, 303-308.
  82. Rapidly Assessing the Activation Conditions and Porosity of Metal-Organic Frameworks Using Thermogravimetric Analysis. McDonald, T. M.; Bloch, E. D.; Long, J. R. Chem. Commun. 2015, 51, 4985-4988.
  83. Counteranion Effects on the Catalytic Activity of Copper Salts Immobilized on the Bipyridine-Functionalized Metal-Organic Framework MOF-253. Valvekens, P.; Bloch, E. D.; Long, J. R.; Ameloot, R.; De Vos, D. E. Cat. Today 2015, 246, 55-59.
  84. NMR Relaxation and Exchange in Metal-Organic Frameworks for Surface Area Screening. Chen, J. J.; Mason, J. A.; Bloch, E. D.; Gygi, D.; Long, J. R.; Reimer, J. A. Microporous Mesoporous Mater. 2015, 205, 65-69.
  85. Comprehensive Study of Carbon Dioxide Adsorption in the Metal-Organic Frameworks M2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Cu, Zn). Queen, W. L.; Bloch, E. D.; Hudson, M. R.; Mason, J. M.; Gonzalez, M. I.; Lee, J.; Gygi, D.; Howe, J. D.; Lee, K.; Darwish, T.; James, M.; Peterson, V. K.; Teat, S. J.; Smit, B.; Neaton, J. R.; Long, J. R.; Brown, C. M. Chem. Sci. 2014, 5, 4569-4581.
  86. Reversible CO Binding Enables Tunable CO/H2 and CO/N2 Separations in Metal-Organic Frameworks with Exposed Divalent Metal Cations. Bloch, E. D.; Hudson, M. R.; Mason, J. A.; Chavan, S.; Crocellà, V.; Howe, J. D.; Lee, K.; Dzubak, A. L.; Queen, W. L.; Zadrozny, J. M.; Geier, S. J.; Lin, L. –C.; Gagliardi, L.; Smit, B.; Neaton, J. B.; Bordiga, S.; Brown, C. M.; Long, J. R. J. Am. Chem. Soc. 2014, 136, 10752-10761.
  87. CO2 Adsorption in Fe2(dobdc): A Classical Force Field Parameterized from Quantum Mechanical Calculations. Borycz, J.; Lin, L. -C.; Bloch, E. D.; Kim, J.; Dzubak, A. L.; Maurice, R.; Semrouni, D.; Lee, K.; Smit, B.; Gagliardi, L. J. Phys. Chem. C 2014, 118, 12230-12240.
  88. Oxidation of Ethane to Ethanol by N2O in a Metal-Organic Framework with Coordinatively Unsaturated Iron(II) Sites. Xiao, D. J.; Bloch, E. D.; Mason, J. A.; Queen, W. L.; Hudson, M. R.; Planas, N.; Borycz, J.; Dzubak, A. L.; Verma, P.; Lee, K.; Bonino, F.; Crocellà, V.; Yano, J.; Bordiga, S.; Truhlar, T. G.; Gagliardi, L.; Brown, C. M.; Long, J. R. Nat. Chem. 2014, 6, 590-595.
  89. Multifunctional, Defect-Engineered Metal-Organic Frameworks with Ruthenium Centers: Sorption and Catalytic Properties. Kozachuk, O.; Luz, I.; Llabrés i Xamena, F. X.; Noei, H.; Kauer, M.; Albada, H. B.; Bloch, E. D.; Marler, B.; Wang, Y.; Muhler, M.; Fischer, R. A. Angew. Chem. Int. Ed. 2014, 53, 7058.
  90. Selective Propene Oligomerization with Nickel(II)-Based Metal-Organic Frameworks. Mlinar, A. N.; Keitz, B. K.; Gygi, D.; Bloch, E. D.; Long, J. R.; Bell, A. T. ACS Catal. 2014, 4, 717-721.
  91. Design of a Metal-Organic Framework with Enhanced Back Bonding for the Separation of N2 and CH4. Lee, K.; Lin, L.-C.; Kim, J.; Isley, W. C.; Dzubak, A.; Verma, P.; Bloch, E. D.; Reed, D. A.; Long, J. R.; Neaton, J.; Smit, B.; Cramer, C. J.; Truhlar, D. G.; Gagliardi, L. J. Am. Chem. Soc. 2014, 136, 698-704.
  92. Hydrocarbon Separations in Metal-Organic Frameworks. Herm, Z. R.; Bloch, E. D.; Long, J. R. Chem. Mater. 2014, 26, 323-338.
  93. Highly Selective Quantum Sieving of D2 from H2 by a Metal-Organic Framework as Determined by Gas Manometry and Infrared Spectroscopy. FitzGerald, S. A.; Pierce, C. J.; Rowsell, J. L. C.; Bloch, E. D.; Mason, J. A. J. Am. Chem. Soc. 2013, 135, 9458-9464.
  94. Selective Adsorption of Ethylene over Ethane and Propylene over Propane in the Metal-Organic Frameworks M2(dobdc) (M = Mg, Mn, Fe, Co, Ni, Zn). Geier, S. J.; Mason, J. A.; Bloch, E. D.; Queen, W. L.; Hudson, M. R.; Brown, C. M.; Long, J. R. Chem. Sci. 2013, 4, 2054-2061.
  95. Impact of Metal and Anion Substitutions on the Hydrogen Storage Properties of M-BTT Metal-Organic Frameworks. Sumida, K.; Stück, D.; Mino, L.; Chai, J. -D.; Bloch, E. D.; Zavorotynska, O.; Murray, L. J.; Dincă, M.; Chavan, S.; Bordiga, S.; Head-Gordon, M.; Long, J. R. J. Am. Chem. Soc. 2013, 135, 1083-1091.
  96. Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites. Bloch, E. D.; Queen, W. L.; Krishna, R.; Zadrozny, J. M.; Brown C. M.; Long, J. R. Science 2012, 335, 1606-1610.
  97. Hydrogen Adsorption in the Metal-Organic Frameworks Fe2(dobdc) and Fe2(O2)(dobdc). Queen, W. L.; Bloch, E. D.; Brown, C. M.; Hudson, M. R.; Mason, J. A.; Murray, L. J.; Ramirez-Cuesta, A. J.; Peterson, V. K.; Long, J. R. Dalton Trans. 2012, 41, 4180-4187.
  98. Acetylene Adsorption on CPO-27-M Metal-Organic Frameworks (M=Fe, Co, and Ni). Chavan, S. M.; Shearer, G. C.; Bloch, E. D.; Bordiga, S. ChemPhysChem 2012, 13, 445-448.
  99. Carbon Dioxide Capture in Metal-Organic Frameworks. Sumida, K.; Rogow, D. L.; Mason, J. A.; McDonald, T. M.; Bloch, E. D.; Herm, Z. R.; Bae, T.-H.; Long, J. R. Chem. Rev. 2012, 112, 724-781.
  100. Selective Binding of O2 over N2 in a Redox-Active Metal-Organic Framework with Open Iron(II) Coordination Sites. Bloch, E. D.; Murray, L. M.; Queen, W. L.; Chavan, S.; Maximoff, S. N.; Bigi, J. P.; Krishna, R.; Peterson, V. K.; Grandjean, F.; Long, G. J.; Smit, B.; Bordiga, S.; Brown, C. M.; Long, J. R. J. Am. Chem. Soc. 2011, 133, 14814-14822.
  101. Metal Insertion in a Microporous Metal-Organic Framework Lined with 2,2′-Bipyridine. Bloch, E. D.; Britt, D.; Doonan, C. J.; Uribe-Romo, F. J.; Furukawa, H.; Long, J. R.; Yaghi, O. M. J. Am. Chem. Soc. 2010, 132, 14382-14384.